Archive for the ‘Chemistry’ Category

Lighting the Way to Hydrogen Fuel Cells

Tuesday, December 15th, 2009
The Advanced Proton Source at Argonne National Laboratory will provide research facilities to explore materials for hydrogen fuel cells.

The Advanced Photon Source at Argonne National Laboratory will provide research facilities to explore materials for hydrogen fuel cells.

Everyone knows that one of President Obama’s big mandates is for more research into green, renewable energy sources. This means a lot more research grants are being given out to people working in these areas. Luckily, the University of Idaho has plenty.

One area Idaho excels in is the development of new battery technology. Besides working on lead acid batteries for hybrid electric vehicles (such as the Humvee they used to test them on, featured in the video below) the university is also looking into hydrogen fuel cells.

Tom Bitterwolf, professor of chemistry, recently got a grant to explore the possibilities of using ruthenium and rhodium for hydrogen fuel cells. The grant will fund the use of the most powerful x-rays in the western hemisphere at Argonne National Laboratory to take an amazingly detailed look at real-time chemical reactions of the two metals.

For more information, check out the recent press release.

Decaf and Nuclear Waste, Together at Last!

Friday, September 18th, 2009
Professor Chien Wai in his lab.

Professor Chien Wai in his lab.

I know what you’re thinking. There’s no way that decaf and nuclear waste go together in any way that could possibly be beneficial, let alone harmless.

But there is.

It turns out that the same basic principles used in the decaffienation of coffee beans and the extraction of alpha acids from massive amounts of hops can also be used to extract usable enriched uranium from the ashes of low-level radioactive waste. The discovery of this process by Chien Wai is just one of several inventions from the University of Idaho that has been licensed to private companies.

In this case, the buyer was international nuclear giant AREVA. They’re taking the technology and constructing a recycling plant near Richland, Washington that will immediately start working on 32 tons of incinerator ash currently sitting around at the nearby enrichment plant.

Curious about the details? Well, read on my friend.

Low-level nuclear waste includes common, everyday objects like air filters, gloves and lab coats that slowly become contaminated during their use anywhere that uses radioactive materials. The most common producers of this type of waste are nuclear energy plants, uranium enrichment plants and hospitals, among others. The sheer volume of this waste is difficult to deal with, so many institutions are allowed to burn it, reducing its volume by 90 percent.

But it turns out that nearly 10 percent of that waste is usable enriched uranium meaning that there is currently about $5 million worth of nuclear fuel just sitting around in the Washington desert.

And nearly 40 years ago, Wai decided to go get it.

The process of decaffeinating coffee beans involves supercritical carbon dioxide. We all know CO2 as a gas or bubbles in our soda. But raise the temperature and pressure just a little bit, and the gas takes on the properties of both a liquid and a gas. It can move directly into a solid object like a gas and dissolve chemicals and compounds like a liquid.

But because CO2 cannot directly dissolve metals, a binding agent called a ligand must be introduced to the equation. Once the ligand is applied, the supercritical CO2 flows through the waste, dissolving both the ligand and the metals bounded to it. Then, when the CO2 is returned to normal pressure, it becomes a gas and evaporates, leaving behind only the extracted metal; enriched uranium in this case.

So in the end, tons of enriched uranium that was previously harmful to the environment will be extracted and reused for energy. The formerly radioactive ash pile will be easier to manage and the whole process is environmentally friendly. No solvents are used, no acids applied and no organic waste is left behind.

If all goes according to plan, the recycling plant will get through the waste in Richland and begin taking in similar waste from other sites around the country. Tons of formerly dangerous waste will no longer be harmful, tons of usable nuclear fuel worth millions of dollars will be recovered, the plant will provide jobs for the community, money will be made for the state of Washington and the University of Idaho, and similar plants will be built around the world.

If you’re looking for global impact, look no further than the technologies coming out of the University of Idaho.

Curious for even more details? See the University of Idaho’s press release, AREVA’s press release or the Idaho Alumni Magazine article on page 20 of the PDF.

Evolving a solution

Wednesday, August 19th, 2009

The genetic algorithm program basically uses a sophisticated method of trial and error to find an optimum solution. A high number of experiments are required for the process, such as the many test beakers filled with algae pictured here.

The genetic algorithm program basically uses a sophisticated method of trial and error to find an optimum solution. A high number of experiments are required for the process, such as the many test beakers filled with algae pictured here.

Scientists here at the University of Idaho are stealing nature’s greatest problem solving invention - evolution. They’ve created a genetic algorithm that basically uses trial and error to find the best solution to a problem.

Here’s how it works.

Say you wanted to solve a problem like, what is the best environment for bacteria to live in while producing biofuel? There are too many variables - like pH level, temperature, nutrients, other organisms - for scientists to ever fully understand the system.

So instead, researchers let the computer create a bunch of different random solutions and test each one. They put the results into the genetic algorithm, which takes common traits of the best solutions, adds some random

mutations and creates a group of “offspring” solutions.

By doing this a whole bunch of times, they eventually find the best solution to the problem.

One graduate student - Kate Kurcharzyk - is using the genetic algorithm to find the best way to naturally break down and dispose of the environmental toxin ammonium perchlorate. Ammonium perchlorate is a substance found in groundwater across the country. It can come from rocket fuels near military bases, industrial manufacturing plants, fertilizers or simply the natural environment. Perchlorates, in general, are highly soluable, move into groundwater easily and are thought to interfere with the normal function of the human thyroid, wreaking havoc on hormones and early childhood development.

If the project goes well, Kurcharzyk will find the best set of circumstances for bacteria to naturally dispose of this growing problem in affected sites around the world.

Super Fast, Super Rare, Super $$$

Thursday, August 6th, 2009

If you thought your high school science experiment was difficult and time-consuming, check this project out!

Eric Brauns, a professor in chemistry, was just awarded $710,000 from the National Science Foundation to build what amounts toan extreme microscope. And if you think the price tag is hefty, try the cost in time on for size - more than two years of assembly required!

The instrument is known as a superfast infrared spectrometer and less than 50 exist in the entire world.

But none exist the way Brauns plans to build his.

In general, an ultrafast infrared spectrometer creates high-powered laser pulses one-ten-trillionth of a second long. To put that in perspective, light can only travel the width of a human hair in that tiny time period. The laser pulses zap whatever is being studied, causing the laser to be scattered and diffracted. By analyzing the pattern of diffraction, scientists can piece together an “image” of the sample’s structure.

But the University of Idaho’s instrument won’t stop there. The instrument creates this laser pulse through a series of optical components. Brauns plans to make use of this by designing the machine to stop the process at several different points, which will create several different kinds of laser pulses.

In effect, the instrument will produce ultrafast pulses tunable from ultraviolet wavelengths to the mid-infrared, allowing many different types of experiments to be conducted. In fact, there are already three other chemistry professors at the University of Idaho waiting in the wings to get their hands on the upcoming instrument.

For more information, and maybe even a clearer explanation, view the full press release.

Getting the Lead Out

Monday, July 20th, 2009

Getting the lead out is an old saying implying someone or something is moving a lot faster. But it recently had a double meaning for the University of Idaho’s College of Engineering. They just signed a Cooperative Research and Development Agreement (CRADA) with the Department of Energy’s Savannah River National Laboratory and private enterprise Exide Technologies to research lead-acid batteries.

So what does it all mean?

Well, basically it means that Exide is going to pump some money into research at Savannah River and the University of Idaho, and when the pair discovers technology making lead-acid batteries better than ever, Exide gets to market it. So the College of Engineering will be working to get the lead-acid batteries out in the world after getting the lead out of the current technology.

This agreement doesn’t come out of the blue. Idaho has a strong history of developing lead-acid batteries for military and commercial use. What it basically come down to is additives. The stuff you fill a battery with is very important. It permits the transmission of electrons from one side to the other, which creates an electric current. The goal is to make that substance as conductive, reactive, light-weight and long-lasting as possible.

Engineers at Idaho and Savannah River recently patented a technology called Porous Hollow Glass Microspheres (PHGMs). Basically, the addition of these tiny spheres filled with more holes than Swiss cheese makes lead-acid batteries better. They decrease the battery’s density, making it lighter, and store large amounts of electrolytes and transport electrons well.

For more information, check out Exide’s press release.